She made her debut in the adult industry in 2011 after being discovered by the famous male porn actor Rocco Siffredi, for who she worked in exclusivity during some time. Valentina Nappi was a Playmate in the Playboy in June 2012 and Penthouse Pet of the Month in November 2013. She went to Art School and studied Art at University. In 2013 she was nominated for several awards such as Best Foreign Performer by XBIZ Award, Best Female Foreign Performer, Best Three-Way Sex Scene, Most Promising New Starlet, Best Boobs by AVN Award. In her free time Ms Nappi writes a column in a magazine on political and social issues.